Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand

Authors
Publication date 2013
Journal Inorganic Chemistry
Volume | Issue number 52 | 4
Pages (from-to) 1682-1684
Organisations
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract The first example of an iridium(I) species bearing a terminal phosphido (PR2-) ligand is reported. This stable compound shows well-behaved reactivity toward various electrophiles, owing to its exposed phosphorus lone pair, allowing reversible protonation, selective alkylation, isolation of a phosphidoborane of iridium, and generation of a phosphido-bridged iridium(I)-gold(I) dinuclear species.
Document type Article
Note With supporting information
Language English
Published at https://doi.org/10.1021/ic302301h
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