S,O-Ligand-Promoted Palladium-Catalyzed C-H Functionalization Reactions of Nondirected Arenes
| Authors |
|
|---|---|
| Publication date | 09-2017 |
| Journal | ACS Catalysis |
| Volume | Issue number | 7 | 9 |
| Pages (from-to) | 6342-6346 |
| Number of pages | 5 |
| Organisations |
|
| Abstract | Pd(II)-catalyzed C-H functionalization of non directed arenes has been realized using an inexpensive and easily accessible type of bidentate S,O-ligand. The catalytic system shows high efficiency in the C-H olefination reaction of electron-rich and electron-poor arenes. This methodology is operationally simple, scalable, and can be used in late-stage functionalization of complex molecules. The broad applicability of this catalyst has been showcased in other transformations such as Pd(II)-catalyzed C-H acetoxylation and allylation reactions. |
| Document type | Article |
| Note | With supplementary file |
| Language | English |
| Related dataset | CCDC 1567101: Experimental Crystal Structure Determination |
| Published at | https://doi.org/10.1021/acscatal.7b02356 |
| Downloads |
Ligand
(Final published version)
Ligand S
(Other version)
|
| Permalink to this page | |