Mechanistic insight in rhodium-mediated carbene polymerization

Authors	A.J.C. Walters
Supervisors	B. de Bruin J.N.H. Reek
Award date	18-12-2013
ISBN	9789461919816
Number of pages	186
Organisations	Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Document type	PhD thesis
Note	Research conducted at: Universiteit van Amsterdam
Language	English
Downloads	Thesis Cover Title pages Table of contents Chapter 1: Carbene insertion into transition metal-carbon bonds: A new tool for catalytic C-C bond formation Chapter 2: Rh-mediated carbene polymerization: From multistep catalyst activation to alcohol-mediated chain-transfer Chapter 3: The influence of crystal packing in the diastereomeric ratio of [(prolinateRh(diene)] complexes and its effect on the selectivity of carbene polymerization reactions Chapter 4: Stereospecific carbene polymerization with oxygenated Rh(diene) species Chapter 5: DFT calculated propagation and termination steps in [(allyl)RhIII(alkyl)]+ mediated carbene polymerization Chapter 6: Potential applications of poly-carbenes: Towards polymeric surfactants and polymeric solar cells? Summary Samenvatting List of publications Dankwoord
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