Co@NH2-​MIL-​125(Ti)​: Cobaloxime-​derived Metal-​Organic Framework-​based Composite for Light-​driven H2 Production

Open Access
Authors
Publication date 2015
Journal Energy & Environmental Science
Volume | Issue number 8 | 1
Pages (from-to) 364-375
Organisations
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract We present a synthetic strategy for the efficient encapsulation of a deriv. of a well-​defined cobaloxime proton redn. catalyst within a photoresponsive metal-​org. framework (NH2- MIL-​125(Ti)​)​. The resulting hybrid system Co@MOF is demonstrated to be a robust heterogeneous composite material. Furthermore, Co@MOF is an efficient and fully recyclable noble metal-​free catalyst system for light-​driven hydrogen evolution from water under visible light illumination.
Document type Article
Note With supplementary information
Language English
Published at https://doi.org/10.1039/c4ee02853h
Published at http://dx.doi.org/10.1039/C4EE02853H
Downloads
Co@NH2-​MIL-​125 (Final published version)
Supplementary materials
Permalink to this page
Back