Electrochemical potential-step investigations of the aerobic interconversions of [NiFe]-hydrogenase from Allochromatium vinosum: insights into the puzzling difference between unready and ready oxidized inactive states.
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| Publication date | 2004 |
| Journal | Journal of the American Chemical Society |
| Volume | Issue number | 126 | 45 |
| Pages (from-to) | 14899-14909 |
| Number of pages | 11 |
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| Abstract | Dynamic electrochemical studies, incorporating catalytic voltammetry and detailed potential-step manipulations, provide compelling evidence that the oxidized inactive state of [NiFe]-hydrogenases termed Unready (or Ni-A) contains a product of partial reduction of O2 that is trapped in the active site. |
| Document type | Article |
| Published at |
https://doi.org/10.1021/ja047939v
(Final published version)
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