Remote Supramolecular Control of Catalyst Selectivity in the Hydroformylation of Alkenes
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| Publication date | 10-01-2011 |
| Journal | Angewandte Chemie |
| Volume | Issue number | 123 | 2 |
| Pages (from-to) | 416-420 |
| Number of pages | 5 |
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| Abstract | The supramolecular interactions between a Rh phosphine catalyst equipped with an anion-binding pocket and alkenes that contain anionic functionalities (see picture) provide an excellent design concept to achieve remote control of the regioselectivity in hydroformylation reactions. The 4-pentenoate and 3-butenylphosphonate, which fit tightly between the Rh center and the pocket, were hydroformylated with unprecedented selectivity. |
| Document type | Article |
| Note | Dedicated to Professor Janusz Jurczak on the occasion of his 70th birthday. - With supplementary file |
| Language | English |
| Related publication | Remote Supramolecular Control of Catalyst Selectivity in the Hydroformylation of Alkenes |
| Published at |
https://doi.org/10.1002/ange.201005173
(Final published version)
https://doi.org/10.1002/anie.201005173
(Other version)
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