Boryl‐Based Pincer Systems: New Avenues in Boron Chemistry
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| Publication date | 08-01-2010 |
| Journal | Angewandte Chemie, International Edition |
| Volume | Issue number | 49 | 2 |
| Pages (from-to) | 252-255 |
| Number of pages | 4 |
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| Abstract | To B or not to B? Incorporation of BH into tridentate ligands has recently allowed the isolation of the first boryl-based pincer complexes. Functionalized diaminoborane and m-carbaborane (see picture) form Ir and Pd complexes, respectively. Novel reactivity, including in catalysis, is expected to result from the M—boryl bond and electronic communication with the specific ligand framework. |
| Document type | Article |
| Language | English |
| Related publication | Boryl‐Pinzettensysteme: neue Wege in der Borchemie |
| Published at | https://doi.org/10.1002/anie.200904795 https://doi.org/10.1002/ange.200904795 |
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