Ligand design in Rh(diene)-mediated "carbene" polymerization; efficient synthesis of high-mass, highly stereoregular, and fully functionalized carbon-chain polymers
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| Publication date | 2010 |
| Journal | Organometallics |
| Volume | Issue number | 29 | 12 |
| Pages (from-to) | 2823-2826 |
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| Abstract | Stereoselective polymerization of "carbenes" from diazo esters mediated by [(L-prolinate)RhI(Me2cod)] allows the formation of highly syndiotactic, fully functionalized carbon-chain polymers with the highest reported molecular weights in high yields, thus providing the best currently available catalyst for this new reaction. |
| Document type | Article |
| Language | English |
| Published at |
https://doi.org/10.1021/om100226d
(Final published version)
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