Coordinated nitrate anions can be directional π-hole donors in the solid state: a CSD study
| Authors | |
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| Publication date | 21-08-2017 |
| Journal | CrystEngComm |
| Volume | Issue number | 19 | 31 |
| Pages (from-to) | 4485-4488 |
| Number of pages | 4 |
| Organisations |
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| Abstract | A comprehensive Cambridge Structure Database evaluation reveals grouping and significant van der Waals overlap of sp2 O-atoms above/below the N-atom of coordinated nitrate anions. Overlap of van der Waals shells increases with increased coordination and 84% of close contacts involve anti-electrostatic NO3−⋯NO3− interactions. |
| Document type | Article |
| Note | With supplementary file |
| Language | English |
| Published at |
https://doi.org/10.1039/c7ce01266g
(Final published version)
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