Coordinated nitrate anions can be directional π-hole donors in the solid state: a CSD study
| Authors |
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| Publication date |
21-08-2017
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| Journal |
CrystEngComm
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| Volume | Issue number |
19 | 31
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| Pages (from-to) |
4485-4488
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| Number of pages |
4
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| Organisations |
-
Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
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| Abstract |
A comprehensive Cambridge Structure Database evaluation reveals grouping and significant van der Waals overlap of sp2
O-atoms above/below the N-atom of coordinated nitrate anions. Overlap
of van der Waals shells increases with increased coordination and 84% of
close contacts involve anti-electrostatic NO3−⋯NO3− interactions.
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| Document type |
Article
|
| Note |
With supplementary file
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| Language |
English
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| Published at |
https://doi.org/10.1039/c7ce01266g
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