Sustainable Phosphorus Chemistry: A Silylphosphide Synthon for the Generation of Value-Added Phosphorus Chemicals
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| Publication date | 28-05-2018 |
| Journal | Angewandte Chemie |
| Volume | Issue number | 130 | 22 |
| Pages (from-to) | 6494-6496 |
| Number of pages | 3 |
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| Abstract | Avoiding white phosphorus: Cummins and Geeson have recently described the conversion of phosphoric acid into the novel bis(trichlorosilyl)phosphide anion (see picture), which serves as a key intermediate in the synthesis of organophosphines, hexafluorophosphate, and phosphine gas in a reaction sequence that does not rely on white phosphorus. |
| Document type | Article |
| Language | English |
| Related publication | Sustainable Phosphorus Chemistry: A Silylphosphide Synthon for the Generation of Value-Added Phosphorus Chemicals |
| Published at | https://doi.org/10.1002/ange.201803692 https://doi.org/10.1002/anie.201803692 |
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