Pre-design and synthesis of a five-fold interpenetrated pcu-type porous coordination polymer and its CO2/CO separation

Authors
  • H. Cao
  • S. Wang
  • Y. Wang
  • H. Lyu
Publication date 14-12-2017
Journal CrystEngComm
Volume | Issue number 19 | 46
Pages (from-to) 6927-6931
Number of pages 5
Organisations
  • Faculty of Science (FNWI)
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract From the viewpoint of mathematics and topology, we proposed a rational design and stabilized the first five-fold interpenetrated porous coordination polymer (PCP) with a pcu topology and extra-framework volume (60.0%) by employing a linear ligand with the length of ∼2 nm. The resulting compound exhibits good CO2 uptake, enabling highly selective separation of CO2 from CO2/CO mixtures.
Document type Article
Note With supplementary materials
Language English
Related dataset CCDC 1574418: Experimental Crystal Structure Determination
Published at
https://doi.org/10.1039/C7CE01649B (Final published version)
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