Amino olefin nickel(I) and nickel(0) complexes as dehydrogenation catalysts for amine boranes

Authors
  • H. Grützmacher
Publication date 2011
Journal Chemical Science
Volume | Issue number 2 | 4
Pages (from-to) 723-727
Organisations
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract A rare paramagnetic organometallic nickel(I) olefin complex can be isolated using the ligand bis(5H-dibenzo[a,d]cyclohepten-5-yl)amine. This complex and related nickel(0) hydride complexes show very high catalytic activity in the dehydrogenation of dimethylamino borane with release of one equivalent of dihydrogen.
Document type Article
Language English
Published at
https://doi.org/10.1039/c0sc00483a (Final published version)
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