Charge Order in NbSe₂

We develop in detail a model of the charge order in NbSe₂ deriving from a strong electron-phonon coupling dependent on the ingoing and outgoing electron momenta as well as the electronic orbitals scattered between. Including both dependencies allows us to reproduce the full range of available experimental observations on this material. The stability of both experimentally-observed charge-ordered geometries (1Q and 3Q) is studied within this model as a function of temperature and uniaxial strain. It is found that a small amount of bulk strain suffices to stabilize the unidirectional order, and that in both ordering geometries, lattice fluctuations arising from the strong electron-phonon coupling act to suppress the onset temperature of charge order, giving a pseudogap regime characterized by local order and strong phase fluctuations.