Reactivity of Rhodium(II) amido/Rhodium(I) aminyl complexes
| Authors |
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| Publication date | 01-10-2018 |
| Journal | Inorganica Chimica Acta |
| Volume | Issue number | 482 |
| Pages (from-to) | 709-716 |
| Number of pages | 8 |
| Organisations |
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| Abstract |
Reaction of the Rh(II) dimer [LRh]2(μ-Br)2 (L = ([2,6-Me2C6H3NCMe]2CH) with the bulky amide LiNH(2,6-iPr2C6H3) leads to a monomeric Rh(II) amide with a T-shape N3Rh arrangement and a pronounced agostic interaction. Reaction with the less bulky LiNH(2,6-Me2C6H3) results in benzylic C-H activation to a binuclear complex with a unique aza-xylylene bridging mode. With LiNHC6H5 we observe initial formation of [LRh]2(μ-NHPh)2 followed by N,C2′ coupling of two anilines. These reactions can be explained based on aminyl radical character of the Rh(II) amides (supported by EPR evidence) and/or involvement of nitrene intermediates.
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| Document type | Article |
| Note | With supplementary files |
| Language | English |
| Related dataset | CCDC 1819936: Experimental Crystal Structure Determination CCDC 1819942: Experimental Crystal Structure Determination CCDC 1819939: Experimental Crystal Structure Determination CCDC 1819941: Experimental Crystal Structure Determination CCDC 1819938: Experimental Crystal Structure Determination CCDC 1819943: Experimental Crystal Structure Determination |
| Published at | https://doi.org/10.1016/j.ica.2018.06.015 |
| Other links | https://doi.org/10.5517/ccdc.csd.cc1z2ssm https://doi.org/10.5517/ccdc.csd.cc1z2sqk https://doi.org/10.5517/ccdc.csd.cc1z2stn https://doi.org/10.5517/ccdc.csd.cc1z2smg https://doi.org/10.5517/ccdc.csd.cc1z2spj https://doi.org/10.5517/ccdc.csd.cc1z2svp |
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