Developing Synthetic Approaches with Non‐Innocent Metalloligands: Easy Access to IrI/Pd0 and IrI/Pd0/IrI Cores

Developing Synthetic Approaches with Non‐Innocent Metalloligands: Easy Access to Ir^I/Pd⁰ and Ir^I/Pd⁰/Ir^I Cores

Authors	C. Tejel L. Asensio M.P. del Rio B. de Bruin J.A. Lopez M.A. Ciriano
Publication date	12-09-2011
Journal	Angewandte Chemie, International Edition
Volume \| Issue number	50 \| 38
Pages (from-to)	8839-8843
Number of pages	5
Organisations	Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract	Guilty as charged is the verdict for anionic Ir complex [Ir(bpa−2 H)(cod)]⁻ in its reactions with Pd^II compounds. The net transfer of two electrons from the Ir complex to Pd allows easy preparation of di‐ and trinuclear π‐imine‐coordinated Pd⁰ compounds such as [{Ir(PyCH₂NCHPy)(cod)}₂Pd] (see picture; C white, Ir red, N blue, Pd yellow). bpa−2 H: doubly deprotonated form of N,N‐bis(2‐picolyl)amine (bpa); cod: 1,5‐cyclooctadiene.
Document type	Article
Note	With supplementary file
Language	English
Related publication	Developing Synthetic Approaches with Non‐Innocent Metalloligands: Easy Access to Ir<sup>I</sup>/Pd<sup>0</sup> and Ir<sup>I</sup>/Pd<sup>0</sup>/Ir<sup>I</sup> Cores
Published at	https://doi.org/10.1002/anie.201104045 https://doi.org/10.1002/ange.201104045
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