Energy landscape of a hydrogen-bonded non-degenerate molecular shuttle
| Authors |
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|---|---|
| Publication date | 2010 |
| Journal | Chemical Communications |
| Volume | Issue number | 46 | 12 |
| Pages (from-to) | 2061-2063 |
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| Abstract | In rotaxane 1, two co-conformations are populated in CDCl3 at temperatures between 250 and 330 K. The thermodynamic parameters show strong enthalpy-entropy compensation, and a non-negligible heat capacity difference between the two forms. |
| Document type | Article |
| Language | English |
| Published at |
https://doi.org/10.1039/b926868e
(Final published version)
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