Supramolecular structure@MXenes for photocatalytic applications - a review

Recently, supramolecules have emerged as innovative and eco-friendly options for photocatalytic applications due to their tunable porous structures and photophysical properties. However, their low thermal stability and chemical stability pose a significant challenge. To address this, combining supramolecules with more stable materials like MXenes, which have a low Fermi energy level, is a useful strategy, in which they can form heterostructures that enhance stability and improve photocatalytic activity. The synthesis process, whether through in situ or post-synthesis modifications, plays a crucial role in controlling the formation of both covalent and non-covalent interactions, as well as the morphology of the heterostructures. These interactions and the resulting morphology significantly influence the recombination and separation of charge carriers (electron-hole pairs), ultimately affecting the stability and recyclability of the heterostructures in photocatalytic applications. In this review, we discuss the importance of supramolecule/MXene heterostructures, detailing their synthesis and morphology, as well as the mechanisms involved in various applications.