Nanosecond photochromic molecular switching of a biphenyl-bridged imidazole dimer revealed by wide range transient absorption spectroscopy

Open Access
Authors
  • T. Yamaguchi
  • M.F. Hilbers
  • P.P. Reinders
  • Y. Kobayashi
Publication date 2015
Journal Chemical Communications
Volume | Issue number 51 | 7
Pages (from-to) 1375-1378
Organisations
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract We demonstrate that a biphenyl-bridged imidazole dimer exhibits fast photochromism with a thermal recovery time constant of similar to 100 ns, which is the fastest thermal back reaction in all reported imidazole dimers. Sub-ps transient absorption spectroscopy reveals that the generation process of the colored species occurs within 1 ps.
Document type Article
Note With supplementary information
Language English
Published at https://doi.org/10.1039/c4cc06001f
Downloads
Supplementary materials
Permalink to this page
Back