Palladium and rhodium allyl complexes in catalysis

Palladium and rhodium allyl complexes in catalysis

Authors	R.J. van Haaren
Supervisors	P.W.N.M. van Leeuwen
Cosupervisors	P.C.J. Kamer G.P.F. van Strijdonck
Award date	15-03-2002
Organisations	Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Document type	PhD thesis
Language	English
Downloads	Thesis Cover Titlepage Contents Chapter 1 General introduction: Towards green chemistry Chapter 2 Palladium catalyzed allylic alkylation (introduction to chapters 3-9) Chapter 3 DFT study of the distortion of the Pd-allyl bond: implications for the regioselectivity of the reaction Chapter 4 Effect of the bite angle of bidentate phosphine ligands on the regioselectivity in allylic alkylation of crotyl complexes. Chapter 5 On the influence of the bite angle on the allylic alkylation of (E) and (Z) substrates: Loss and retention of double bond stereochemistry. Chapter 6 On the influence of the bite angle of bidentate P-N ligands on the regioselectivity of the allylic alkylation of monosubstituted allyl moieties. Chapter 7. An X-ray study towards the effect of the bite angle of bidentate phosphine ligands on the geometry of palladium(allyl) complexes: implications for the regioselectivity in the allylic alkylation of a disubstituted allyl moiety. Chapter 8. The effect of ligand donor atoms of wide bite angle ligands on the regioselectivity in the palladium catalyzed allylic alkylation of a disubstituted allyl moiety. chapter 9 Allylic alkylation: an evaluation. Chapter 10 New insights in the mechanism of the palladium catalyzed methoxycarbonylation of cinnamyl chloride. Chapter 11 Rhodium-allyl chemistry Chapter 12 Summary Hoofdstuk 13 Samenvatting Cover
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Palladium and rhodium allyl complexes in catalysis