IR spectroscopy on jet-cooled isolated two-station rotaxanes
| Authors | |
|---|---|
| Publication date | 2011 |
| Journal | The Journal of Physical Chemistry. A |
| Volume | Issue number | 115 | 34 |
| Pages (from-to) | 9669-9675 |
| Organisations |
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| Abstract | High-resolution IR spectroscopy has been employed to study isolated, switchable [2]rotaxanes. IR absorption spectra of two-station rotaxanes, their separate thread, and macrocycle components, as well as those of the individual stations incorporated into the thread, have been measured in the 1800-1000 cm-1 region. These spectra have been fully analyzed, aided by quantum chemical predictions of the IR spectra. From these analyses, a comprehensive picture emerges of the conformational structure and binding interactions between the mechanically interlocked components of the rotaxane |
| Document type | Article |
| Note | PT: J; SI: SI; TC: 1; UT: WOS:000294146400040 |
| Language | English |
| Published at |
https://doi.org/10.1021/jp200909v
(Final published version)
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| Permalink to this page | |
