Synthesis of α-Substituted Diphenylphosphinocarboxylic Acids and Their Palladium Complexes

Authors
Publication date 01-2017
Journal Synlett
Volume | Issue number 28 | 2
Pages (from-to) 221-224
Organisations
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract A general and efficient synthesis of α-substituted phosphinoacetic acids using simple esters and diphenylchlorophosphine–borane as readily available starting materials is here described. The formation and structure of the corresponding palladium complex derived from 2-ethyl diphenylphosphinoacetic acid is also reported.
Document type Article
Note With Supporting Information
Language English
Related dataset CCDC 1489246: Experimental Crystal Structure Determination
Published at https://doi.org/10.1055/s-0036-1588328
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