Behind the Science: Cheap and Diastereoselective ß-Lactam Formation
| Authors |
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| Publication date | 05-04-2018 |
| Journal | ChemistryViews |
| Organisations |
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| Abstract | Professor Bas de Bruin, University of Amsterdam, The Netherlands, and Dr. Karen Hindson, Senior Editor of the European Journal of Inorganic Chemistry, talked about Bas de Bruin’s article on a one-pot route to ß-lactams, amides, and esters. He used cobalt porphyrinoid metalloradicals to produce a stable carbene radical that provided in situ access to a ketene intermediate. The desired products formed in the presence of an appropriate nucleophile. |
| Document type | Article |
| Language | English |
| Related publication | [Co(MeTAA)] Metalloradical Catalytic Route to Ketenes via Carbonylation of Carbene Radicals |
| Published at |
https://doi.org/10.1002/chemv.201800025
(Final published version)
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