Intermolecular C-H activation with an Ir-METAMORPhos piano-stool complex: multiple reaction steps at a reactive ligand
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| Publication date | 2015 |
| Journal | Chemical Communications |
| Volume | Issue number | 51 | 82 |
| Pages (from-to) | 15200-15203 |
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| Abstract | Substrate activation by means of a reactive ligand is a topic of much interest. Herein we describe a stoichiometric anti-Markovnikov C-N bond formation involving ligand reactivity in multiple steps along the reaction coordinate, including ligand assisted substrate (de)protonation and C-N bond formation, as illustrated by a combined experimental, spectroscopic and computational study. This affords a highly unusual four-membered iridacycle bearing an exo-cyclic C=C double bond. |
| Document type | Article |
| Language | English |
| Published at | https://doi.org/10.1039/c5cc05916j |
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