Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster

Open Access
Authors
  • C. Lichtenberg
  • L. Viciu
  • M. Vogt
  • R.E. Rodríguez-Lugo
  • M. Adelhardt
  • J. Sutter
  • M.M. Khusniyarov
  • K. Meyer
  • B. de Bruin ORCID logo
  • E. Bill
  • H. Grützmacher
Publication date 2015
Journal Chemical Communications
Volume | Issue number 51 | 73
Pages (from-to) 13890-13893
Organisations
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis, EPR and Mossbauer spectroscopy, and magnetic susceptibility measurements.
Document type Article
Note With supplementary information
Language English
Published at https://doi.org/10.1039/c5cc04908c
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