Self-assembly of a confined rhodium catalyst for asymmetric hydroformylation of unfunctionalized internal alkenes

Authors
Publication date 2012
Journal Journal of the American Chemical Society
Volume | Issue number 134 | 6
Pages (from-to) 2860-2863
Organisations
  • Faculty of Science (FNWI) - Swammerdam Institute for Life Sciences (SILS)
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract A chiral supramolecular ligand has been assembled and applied to the rhodium-catalyzed asymmetric hydroformylation of unfunctionalized internal alkenes. Spatial confinement of the metal center within a chiral pocket results in reversed regioselectivity and remarkable enantioselectivities.
Document type Article
Language English
Published at
https://doi.org/10.1021/ja211455j (Final published version)
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