Ligand Self-Sorting and Nonlinear Effects in Dinuclear Asymmetric Hydrogenation: Complexity in Catalysis

Authors
Publication date 2013
Journal Chemistry - A European Journal
Volume | Issue number 19 | 32
Pages (from-to) 10458-10462
Organisations
  • Faculty of Science (FNWI) - Van 't Hoff Institute for Molecular Sciences (HIMS)
Abstract : Nonlinear effects are observed in asymmetric hydrogenation reactions if self-sorted dinuclear complexes are generated. The nature of the substrate also influences this effect, because it affects the solubility of racemic self-sorted homochiral dinuclear complexes (see scheme).
Document type Article
Note With supporting information
Language English
Published at https://doi.org/10.1002/chem.201301966
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